SHERWIN-WILLIAMS COMPANY -- DTM ACRYLIC GLOSS ENAMEL- -- 8010-01-334-3002
===================== Product Identification ===================== Product ID:DTM ACRYLIC GLOSS ENAMEL- MSDS Date:07/01/1995 FSC:8010 NIIN:01-334-3002 Status Code:A === Responsible Party === Company Name:SHERWIN-WILLIAMS COMPANY Address:101 PROSPECT AVENUE City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-566-2902 Emergency Phone Num:1-216-566-2917 CAGE:54636 === Contractor Identification === Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:2-(2-METHOXYETHOXY)-ETHANOL VP = 1.0 CAS:111-77-3 RTECS #:KL6125000 = Wt:4. Ingred Name:2-(2-BUTOXYETHOXY)-ETHANOL VP=0.1 CAS:112-34-5 RTECS #:KJ9100000 Ingred Name:ETHYLENE GLYCOL VP= 0.1 CAS:107-21-1 RTECS #:KW2975000 OSHA PEL:50PPM OSHA STEL:50 PPM ACGIH TLV:50 PPM ACGIH STEL:50 PPMM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:OXO-TRIDECYL ACETATE. VP= 0.01 CAS:108419-35-8 = Wt:3. Ingred Name:NONYLPHENOXY POLYETHOXY ETHANOL CAS:9016-45-9 RTECS #:AX0247000 = Wt:1. Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 = Wt:2. OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 ACGIH STEL:5 MG/M3 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:(TO MINIMIZE EXPOSURE FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION, AND PERSONAL) ACUTE HEALTH HAZARDS: IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION . EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCOIUSNESS AND DEATH. HEADACHE, DIZZINESS, NUASEA, AND LOSS OF COORDINATION ARE INDICATIONS OF OXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND I TCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. * Effects of Overexposure:*CHRONIC HEALTH HAZARDS: CRYSTALLINE SILICA (QUARTZ, CRISOBALITE) IS LISTED BY IARC AND NTP. LONG TERM EXPOSURE TO HIGH LEVELS OF SILCA DUST, WHICH CAN OCCUR ONLY WHEN SANDING OR ABRADING THE DRY F ILM, MAY CAUSE LUNG DAMAGE (SILICOSIS) AND POSSIBLY CANCER. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITIONOR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION,WEAR ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST INGREDIENTS.WHEN SANDING,WIREBR USHING,ABRADING,BURNING/WELDING DRIED FILM,WEARPARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST NONVOLATILE MATERIALS IN SECTION II Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO MATERIALS IN SECTION II IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. Protective Gloves:WEAR GLOVES RECOMMENDED BY GLOVE SUPPLIER FOR PROTECTION AGAINST INGREDIENTS. Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDE SHIELDS. Other Protective Equipment:REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. WASH HANDS AFTER USING. Supplemental Safety and Health COATINGS MAY CONTAIN NUISANCE PARTICULATES(LISTED "AS DUST"IN SECTION II)WHICH MAY BE PRESENT@HAZARDOUS LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM.IF NO SPECIFIC DUSTS ARE LISTED IN SECTION II, APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV,10MG/M3(TOTAL DUST),OSHA PEL15MG/M3,5MG/M3(RESPIRABLE FRACTION) ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F B.P. Text:212F Vapor Density:>AIR pH:9.0 - 9.5 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:54 - 79% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO2, CO, OXIDES OF METALS LISTED IN INGREDIENTS. =================== Toxicological Information =================== Toxicological Information:ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS AND MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER OR BY GAVAGE. THERE IS NO EVIDENCE TO INDICAT E IT CAUSES BIRTH DEFECTS IN HUMANS. PROLONGED OR OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION II MAY CAUSE ADVERSE EFFECTS TO THE LIVER AND URINARY SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODUCTS IS NOT HAZARDOUS AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER. DISPOS E OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING POLLUTION. ===================== Regulatory Information ===================== SARA Title III Information:THE FOLLOWING INGREDIENTS ARE SUBJECT TO REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 313, 40 CFR PART 372.65C 1) 2-(2-METHOXYETHOXY)-ETHANOL 2) 2-(2-B UTOXYETHOXY)-ETHANOL 3) ETHYLENE GLYCOL State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING! THESE PRODUCTS CONTAIN A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.