SUNSHINE MAKERS, INC. -- SIMPLE GREEN ALL-PURPOSE CLEANER FOAM -- -
===================== Product Identification ===================== Product ID:SIMPLE GREEN ALL-PURPOSE CLEANER FOAM MSDS Date:01/01/2003 Kit Part:=== Responsible Party === Company Name:SUNSHINE MAKERS, INC. Address:15922 Pacific Coast Highway City:Huntington Harbour State:CA ZIP:9264 Country:US Info Phone Num:800-228-0709/562-795-6000 Resp. Party Other MSDS Num.:800-255-3924 === Contractor Identification === Company Name:SPI INCORPORATED Address:3360 E PICO BLVD Box:City:LOS ANGELES State:CA ZIP:90023 Country:US Phone:323-269-9231 CAGE:UO207 ============= Composition/Information on Ingredients ============= Ingred Name:2-Butyoxyethanol, Glycol Ether EB CAS:111-76-2 < Wt:<5 OSHA PEL:25 ppm ACGIH TLV:25 ppm, (SKIN) Ingred Name:Butane CAS:106-97-8 = Wt:4 OSHA PEL:800 ppm ACGIH TLV:800 ppm Ingred Name:Propane CAS:74-98-6 = Wt:1 OSHA PEL:1000 ppm ACGIH TLV:ASPHYXIANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:Yes Skin:Yes Ingestion:Yes Health Hazards Acute and Chronic:Adverse effects on human health are not expected from Foaming Simple GreenŽ. Foaming Simple GreenŽ is a mild eye irritant; mucous membranes may become irritated by concentrate-mist. Foaming Simple GreenŽ is not likely to irritate the skin in the majority of users. Repeated daily application to the skin without rinsing, or continuous contact of Foaming Simple GreenŽ on the skin may lead to temporary, but reversible, irritation. Explanation of Carcinogenicity:Foaming Simple GreenŽ is non-mutagenic and non-carcinogenic. None of the ingredients in Foaming Simple GreenŽ are regulated or listed as potential cancer agents by Federal OSHA, NTP, or IARC. Medical Cond Aggravated by Exposure:Medical Conditions Aggravated by Exposure: No aggravation of existing medical conditions is expected; some dermalsensitive users may react to dermal contact by Foaming Simple GreenŽ. ======================= First Aid Measures ======================= First Aid:Eye contact: Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15 minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper and lower lids during rinsing. Get medical attention if irritation persists. Skin contact: Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if reaction persists. Swallowing: Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset occurs, consult physician. Inhalation: Intentional concentration of propellant could cause respiratory irritation, headache, nausea, fatigue, drowsiness, impaired coordination. Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Get medical attention. ===================== Fire Fighting Measures ===================== Extinguishing Media:Foaming Simple GreenŽ contains a flammable propellant and firefighters should wear self-contained breathing apparatus when fighting fires containing or around this product. Shut off all sources of ignition if possible. Keep containers cool with water spray to prevent rupture. Ventilate area. Contain spill and dike if possible. For leaks and spills that have not ignited, water spray can be used to disperse the flammable vapor and protect personnel attempting to stop the leak. Do not use direct stream of water because the flammable portion will float and can be reignited. Fire Fighting Procedures:Extinguishing medium as appropriate for combustibles in area. Unusual Fire/Explosion Hazard:Firefighters should wear SCBA's in a positive pressure mode with full-face shield. The flammable components are heavier than air and may travel long distances and accumulate in low areas or spread along ground from handling site. Eliminate all sources of ignition as vapor may ignite. Carbon oxides may be formed. NOTE: Per the DOT Flame Extension Test, Foaming Simple GreenŽ did not produce a flame projection or flashback. ================== Accidental Release Measures ================== Spill Release Procedures:Recover usable material by convenient method; residual may be removed by wipe or wet mop. Ventilate area especially low places where heavy vapors might collect. Extinguish all ignition sources. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store in tightly sealed containers. Keep away from heat, sparks, open flame and out of direct sunlight. Store below 120 °F. Do not puncture or incinerate (burn) cans. Do not stick pin, nail or any other sharp object into opening on top of can. MODE:IATA BASIC DESCRIPTION:Consumer Commodity [Less than 17 fl. oz. (500 ml)] Aerosols, flammable 17 fl. oz. (500 ml) or greater] ADDITIONAL DESCRIPTIVE:9, ID8000, 2.1, UN1950 PKG. INSTRUCTION:910, Y203, LTD QTY ER INFO.:ERG 171, ERG 126 MODE:IMDG BASIC DESCRIPTION:Aerosols [For all sizes] ADDITIONAL DESCRIPTIVE:2, UN1950 PKG. INSTRUCTION: ER INFO.:ERG 126, EmS 2-13, MFAG 620 MODE:DOT (40 CFR) BASIC DESCRIPTION:Consumer Commodity [For all sizes] ADDITIONAL DESCRIPTIVE:ORM-D PKG. INSTRUCTION: ER INFO.:ERG 171 MODE:UPS Air BASIC DESCRIPTION:Consumer Commodity [For all sizes] ADDITIONAL DESCRIPTIVE:ORM-D-AIR PKG. INSTRUCTION: ER INFO.:ERG 171 Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:No special precautions required. Ventilation:No special ventilation is required during normal use. Protective Gloves:No special precautions required; rinse completely from skin after contact. reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if reaction persists. Eye Protection:Caution, including reasonable eye protection, should always be used to avoid eye contact. Other Protective Equipment:No special requirements under normal use conditions. Work Hygienic Practices:Wash or rinse hands before touching eyes or contact lenses. Follow standard hygienic practices for handling cleaning agents. Supplemental Safety and Health The Foaming Simple GreenŽ formulation presents no health hazards to the user, other than mild eye irritancy. ================== Physical/Chemical Properties ================== Boiling Pt:100.6 °C Vapor Pres:18mmHg@20°C;23.5mmHg@26°C Spec Gravity:1.020 VOC Pounds/Gallon:50 pH:9.35 Solubility in Water:Completely soluble in water. Appearance and Odor:White foam, mild soap odor. Foaming Simple GreenŽ has a characteristic odor that is not indicative of any hazardous situation. Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stability Condition to Avoid:Nonreactive. Foaming Simple GreenŽ is stable, and will not react with water or oxidizers. Hazardous polymerization will not occur. Conditions to Avoid Polymerization: =================== Toxicological Information =================== Toxicological Information:Nonhuman Toxicity (data for Simple Green ) Acute Mortality Studies:Oral LD50 (rat): >5.0 g/kg body weight Dermal LD50 (rabbit): >2.0 g/kg body weight Dermal Irritation: Only mild, but reversible, irritation was found in a standard 72-hr test on rabbits. A value of 0.2 (non-irritating) was found on a scale of 8. Eye Irritation: With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15 (mild irritant) on a scale of 110. Subchronic dermal effects: No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only female body weight gain was affected. Detailed microscopic examination of all major tissues showed no adverse changes. Fertility Assessment by Continuous Breeding: The Simple GreenŽ formulation had no adverse effect on fertility and reproduction in CD-1 mice with continuous administration for 18 weeks, and had no adverse effect on the reproductive performance of their offspring. ===================== Ecological Information ===================== Ecological:Biodegradability:Like Simple GreenŽ, Foaming Simple GreenŽ is readily decomposed by naturally occurring microorganisms. The biological oxygen demand (BOD), as a percentage of the chemical oxygen demand (COD), will approximate 60% after 11 days. In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in six to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose, which was used as a control for comparison. Environmental Toxicity Information:Foaming Simple GreenŽ is considered practically non-toxic per EPAs aquatic toxicity scale. ==================== Disposal Considerations ==================== Waste Disposal Methods:Foaming Simple GreenŽ is fully water soluble and biodegradable and will not harm sewage-treatment microorganisms if disposal by sewer or drain is necessary. Dispose of in accordance with all applicable local, state, and federal laws. Containers: Do not throw empty containers in trash compactor or into fire. Do not store in direct sun. =================== MSDS Transport Information =================== Transport Information:Store in tightly sealed containers. Keep away from heat, sparks, open flame and out of direct sunlight. Store below 120 °F. Do not puncture or incinerate (burn) cans. Do not stick pin, nail or any other sharp object into opening on top of can. ===================== Regulatory Information ===================== SARA Title III Information:The Butyl Cellosolve in Foaming Simple GreenŽ is part of a chemical category (glycol ethers) regulated by the Emergency Planning and Community Right-to-Know Act (SARA, Title III, section 313); therefore, a reporting requirement exists in the U.S.A. Federal Regulatory Information:Based upon chemical analysis Foaming Simple GreenŽ contains no known EPA priority pollutants, heavy metals, or chemicals listed under RCRA, CERCLA, or CWA. Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or inorganic constituents. State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.